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Professor
Joseph Black
Joseph
Black, the son of a wine merchant, was born in Bordeaux, France,
and studied languages and natural philosophy, and later, medicine
and chemistry at Glasgow University (1746-50). He moved to Edinburgh
in 1751, where he presented his thesis in 1754. Black published
very little and the thesis, expanded and published as Experiments
upon Magnesia Alba, Quicklime, and some other Alcaline Substances
(1756), contained his most influential work. The paper in fact
marked the beginning of modern chemistry. Black investigated quantitatively
the cycle of reactions: limestone >> quicklime >>
slaked lime >> limestone, and showed that the gas evolved
('fixed air' or carbon dioxide) is distinct from and a constituent
of atmospheric air, and is the cause of the effervescence of limestone
with acids. He proved that mild alkalis will become more alkaline
when they lose carbon dioxide and they are converted back to mild
alkalis through reabsorption of the gas.
Black's
other great discovery was that of latent heat (the heat required
to produce a change of state). The concept of latent heat came
to him in 1757 and the experimental determination of the latent
heat of fusion of ice was made in 1761. The next year he determined
the latent heat of formation of steam. Black also distinguished
the difference between heat and temperature and conceived the
idea of specific heat.
Black
was professor of medicine and lecturer in chemistry at Glasgow
(1756-66) and then professor of chemistry at Edinburgh for the
rest of his life. Black's lectures, which he gave for over 30
years, were immensely popular and were published in 1803.
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